Spaghettification is about gravitational tidal forces pulling all your molecules away from each other.
Magnetar vaporization is about the electromagnetic force (which is much stronger than gravity) tearing your molecules themselves apart. (Although the gravitational tidal forces around a magnetar would also be unpleasant.)
Magnetar vaporization would not be painful: Pain requires nerves, and your nerves would be gone. It also requires a brain to receive the nerve impulses and that would be gone too.
Spaghettification could be painful especially around a medium-sized black hole because it would happen slowly enough that you could feel your body being torn apart. Around a small black hole it would happen so fast that it would be essentially painless. Around a super-large black hole like the one at the center of our galaxy the tidal forces might be so gentle you'd never be spaghettified at all.